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Is described on the basis of quantum mechanical calculations with The comparison with other known tetraradicals as well as biradicals ![]() In addition to the synthesis of P-centered tetraradicals, Furthermore, it was demonstrated that tetraradical 1 can be utilized for the activation of small molecules such as molecular Isolating a persistent P-centered singlet tetraradical, 2,6-diaza-1,3,5,7-tetraphospha- s-hydrindacene-1,3,5,7-tetrayl ( 1), in good Sites linked by an N–R unit and bridged by a benzene moiety.īy varying the size of the substituent R, we finally succeeded in We investigated the introduction of four phosphorus-based radical Starting from an s-hydrindacenyl skeleton, Herein, we describe the search for persistent phosphorus-centered ![]() Very low stability has hampered their isolation and use in small-moleculeĪctivation. Thoroughly studied, much less is known about tetraradicals, as their While main-group-element-centered biradicals have been Are important intermediates in the process of bond formationĪnd breaking. ![]() ![]() Each character has their own vampiric abilities and disciplines that you can upgrade individually to suit your preferred approach. Progress in the game through their intertwined destinies, deal with their different points of view and use their character sheets to try to separate the truth from the lies. Play as 3 vampires who are over a hundred years old. With rumours of plots, murders and power struggles, you must work in the shadows to protect your Sect in a pulsating investigation that plunges Boston into chaos. An iron hand in a velvet glove, she intends to assert her power and respect the Masquerade, the vampiric law designed to ensure humans never learn of the existence of these creatures of the night. Hazel Iversen, the Swan, is the new Prince of the Boston Camarilla. 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Updated re-releases are also different from Collector's Editions and should not be confused. When a classic game is recreated entirely for today, it's a remake when fans consider the re-release (remake or otherwise) to be better than the original, it's a Polished Port. Or worse if it is released for a different console than the original, and they don't own that console. ![]() Of course, this can be particularly annoying to people who purchased the original, who now have to pay up to $40 (or more) for a game they mostly already own. note Or a Board Game, Card Game, Tabletop Game, what have you. Common features include more game modes, new gameplay segments, shinier graphics, harder difficulty settings, new weapons and costumes, an added epilogue, a Bonus Dungeon (especially for role-playing games), improved performance due to being designed to run on a more powerful later generation console, and so forth. When a bigger and better version of a game is released after the original. 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